Home Back

Activity Coefficient using Gamma-Phi Formulation of VLE Calculator

Activity Coefficient Formula:

\[ \gamma = \frac{y_{Gas} \times \phi \times P_T}{x_{Liquid} \times P_{sat}} \]

Pa
Pa

Unit Converter ▲

Unit Converter ▼

From: To:

1. What is Activity Coefficient in VLE?

Definition: The activity coefficient (γ) quantifies the deviation of a component's behavior from ideal solution behavior in vapor-liquid equilibrium (VLE).

Purpose: It's crucial for accurate phase equilibrium calculations in chemical engineering and thermodynamics.

2. How Does the Gamma-Phi Formulation Work?

The calculator uses the formula:

\[ \gamma = \frac{y_{Gas} \times \phi \times P_T}{x_{Liquid} \times P_{sat}} \]

Where:

Explanation: This formulation relates the vapor and liquid phase compositions through thermodynamic coefficients and pressures.

3. Importance of Activity Coefficient

Details: Accurate γ values are essential for designing distillation columns, predicting phase behavior, and modeling chemical processes.

4. Using the Calculator

Tips: Enter all required parameters. Mole fractions should be between 0 and 1. All other values must be positive.

5. Frequently Asked Questions (FAQ)

Q1: What does an activity coefficient of 1 mean?
A: γ=1 indicates ideal solution behavior where Raoult's Law applies perfectly.

Q2: How do I obtain the fugacity coefficient?
A: φ can be calculated from equations of state or obtained from experimental data.

Q3: What are typical values for activity coefficients?
A: γ can range from 0 to ∞, but typically between 0.1 and 10 for most systems.

Q4: When would I need this calculation?
A: For non-ideal VLE systems common in hydrocarbon processing, alcohol-water mixtures, etc.

Q5: What if my γ result is very large or very small?
A: Extreme values may indicate azeotropic behavior or immiscibility - verify your inputs.

Activity Coefficient Calculator© - All Rights Reserved 2025