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Backward Reaction Rate Constant for 2nd Order Opposed by 2nd Order Reaction Calculator

Backward Reaction Rate Constant Formula:

\[ k_b' = \frac{k_f' \times (A_0 - x_{eq}) \times (B_0 - x_{eq})}{x_{eq}^2} \]

m³/(mol·s)
mol/m³
mol/m³
mol/m³
m³/(mol·s)

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1. What is Backward Reaction Rate Constant for 2nd Order?

Definition: The backward reaction rate constant for a 2nd order reaction is the proportionality constant relating the rate of the chemical reaction to the concentration of reactants or products in a backward reaction.

Purpose: It helps chemists and chemical engineers understand and predict the behavior of reversible chemical reactions at equilibrium.

2. How Does the Calculator Work?

The calculator uses the formula:

\[ k_b' = \frac{k_f' \times (A_0 - x_{eq}) \times (B_0 - x_{eq})}{x_{eq}^2} \]

Where:

Explanation: The formula calculates the backward rate constant based on the forward rate constant and the equilibrium concentrations of the reactants.

3. Importance of Backward Reaction Rate Constant

Details: Understanding both forward and backward rate constants is crucial for predicting reaction behavior, designing chemical reactors, and optimizing reaction conditions.

4. Using the Calculator

Tips: Enter the forward rate constant, initial concentrations of both reactants, and the equilibrium concentration. All values must be positive numbers.

5. Frequently Asked Questions (FAQ)

Q1: What units should I use for concentrations?
A: The calculator uses mol/m³ for all concentration values. Convert your units if necessary.

Q2: Can this calculator be used for first-order reactions?
A: No, this formula is specific for second-order reactions. First-order reactions have a different relationship.

Q3: What if my equilibrium concentration is zero?
A: The equilibrium concentration must be greater than zero for the calculation to work (division by zero is undefined).

Q4: How accurate is this calculation?
A: The calculation is mathematically exact for ideal second-order reactions following this mechanism.

Q5: What if (A₀ - xeq) or (B₀ - xeq) is negative?
A: This would indicate an error in input values, as equilibrium concentration cannot exceed initial concentrations.

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