Critical Pressure Formula:
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Definition: Critical pressure is the minimum pressure required to liquefy a substance at its critical temperature.
Purpose: This calculator determines the critical pressure using Wohl's equation of state, which is important for understanding gas behavior under extreme conditions.
The calculator uses the formula:
Where:
Explanation: The formula relates critical pressure to other critical parameters in Wohl's model of real gas behavior.
Details: Critical pressure is essential for designing high-pressure systems, understanding phase behavior, and in petroleum and chemical engineering applications.
Tips: Enter the critical temperature in Kelvin and critical molar volume in cubic meters per mole. Both values must be positive.
Q1: What is the Wohl's equation of state?
A: It's a cubic equation of state used to model real gas behavior, similar to van der Waals but with different parameters.
Q2: What are typical values for critical parameters?
A: Critical temperatures range from 33K (hydrogen) to 1900K (tungsten hexafluoride). Critical volumes are typically 0.0001-0.0005 m³/mol.
Q3: How accurate is this calculation?
A: It provides theoretical values based on Wohl's model. Actual experimental values may differ slightly.
Q4: Can I use this for any gas?
A: Yes, but accuracy varies. It works best for simple, non-polar molecules.
Q5: What units does the calculator use?
A: Temperature in Kelvin, volume in m³/mol, and pressure in Pascals (SI units).