Critical Temperature Formula:
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Definition: Critical Temperature given RKE and b is the highest temperature at which the substance can exist as a liquid. At this phase boundaries vanish, and the substance can exist both as a liquid and vapor.
Purpose: This calculator determines the critical temperature using the Redlich-Kwong equation parameter b and critical pressure.
The calculator uses the formula:
Where:
Explanation: The formula relates the critical temperature to the Redlich-Kwong parameter b and critical pressure through fundamental thermodynamic relationships.
Details: Critical temperature is essential for understanding phase behavior, designing chemical processes, and predicting gas liquefaction conditions.
Tips: Enter the Redlich-Kwong parameter b and critical pressure in Pascals. Both values must be positive numbers.
Q1: What is the Redlich-Kwong parameter b?
A: It's an empirical parameter characteristic to the Redlich-Kwong equation of state for real gases.
Q2: What units should I use for critical pressure?
A: The calculator expects Pascals (Pa) as input, but you can convert from other units (1 atm = 101325 Pa).
Q3: Why is the universal gas constant used?
A: The constant R appears in the derivation of the Redlich-Kwong equation and connects macroscopic and molecular thermodynamics.
Q4: How accurate is this calculation?
A: This provides a theoretical estimate based on the Redlich-Kwong model, which works well for many non-polar gases.
Q5: Can I use this for any gas?
A: The Redlich-Kwong equation works best for simple, non-polar molecules. For complex molecules, more sophisticated equations may be needed.