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Definition: This calculator determines the dissociation constant of a second acid (Ka₂) based on the dissociation constant of a first acid (Ka₁) and their respective degrees of dissociation.
Purpose: It helps chemists and students compare the relative strengths of acids based on their dissociation behavior in solution.
The calculator uses the formula:
Where:
Explanation: The formula relates the dissociation constants of two acids through the square of the ratio of their degrees of dissociation.
Details: The dissociation constant (Ka) quantifies acid strength in solution. A higher Ka value indicates a stronger acid that dissociates more completely.
Tips: Enter the known dissociation constant (Ka₁) and both degrees of dissociation (α₁ and α₂). All values must be positive numbers, with degrees of dissociation between 0 and 1.
Q1: What is degree of dissociation?
A: The degree of dissociation (α) is the fraction of acid molecules that dissociate into ions in solution, ranging from 0 (no dissociation) to 1 (complete dissociation).
Q2: Why is the ratio squared in the formula?
A: The square relationship comes from the equilibrium constant expression for weak acid dissociation, where concentrations are raised to their stoichiometric coefficients.
Q3: What units does Ka have?
A: The acid dissociation constant is dimensionless when using activities, but often given in mol/L when using concentrations.
Q4: Can I use this for bases?
A: No, this formula is specific for acids. Bases have their own dissociation constant (Kb).
Q5: What's a typical range for Ka values?
A: Strong acids have Ka > 1, weak acids have Ka between 10⁻³ and 1, and very weak acids have Ka < 10⁻³.