Formula Used:
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Definition: This calculator determines the dissociation constant of a second base (Kb₂) based on the dissociation constant of a first base (Kb₁) and their respective degrees of dissociation.
Purpose: It helps chemists and students compare the relative strengths of two bases when their degrees of dissociation are known.
The calculator uses the formula:
Where:
Explanation: The formula relates the dissociation constants of two bases through the square of the ratio of their degrees of dissociation.
Details: Understanding base dissociation constants is crucial for predicting base strength, pH calculations, and chemical equilibrium studies.
Tips: Enter the dissociation constant of base 1 (Kb₁), degree of dissociation for both bases (α₁ and α₂). All values must be > 0 and degrees of dissociation typically range between 0 and 1.
Q1: What is the degree of dissociation?
A: It's the fraction of molecules that dissociate into ions in solution, ranging from 0 (no dissociation) to 1 (complete dissociation).
Q2: Why is the ratio squared in the formula?
A: The square relationship comes from the equilibrium constant expression for weak base dissociation.
Q3: What units should I use for Kb values?
A: The calculator works with any consistent units, but typically Kb is expressed in mol/L.
Q4: Can I use this for strong bases?
A: No, this formula applies only to weak bases where dissociation is incomplete (α < 1).
Q5: How accurate is this calculation?
A: It provides a good estimate when comparing bases under similar conditions (temperature, concentration).