Gibbs Free Energy Formula:
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Definition: Gibbs Free Energy is a thermodynamic potential that measures the maximum reversible work that may be performed by a thermodynamic system at constant temperature and pressure.
Purpose: It helps predict whether a process will occur spontaneously at constant pressure and temperature.
The calculator uses the formula:
Where:
Explanation: The formula accounts for the deviation from ideal gas behavior using fugacity.
Details: Accurate calculation of Gibbs Free Energy is crucial for understanding chemical reactions, phase transitions, and other thermodynamic processes.
Tips: Enter the ideal gas Gibbs energy, temperature (must be > 0K), fugacity, and pressure (both must be > 0Pa). The calculator will compute the real Gibbs Free Energy.
Q1: What is fugacity?
A: Fugacity is a thermodynamic property that measures the "effective pressure" of a real gas, accounting for non-ideal behavior.
Q2: Why do we need both fugacity and pressure?
A: The ratio f/P measures the deviation from ideal gas behavior. For ideal gases, f = P and the correction term becomes zero.
Q3: What units should I use?
A: Use consistent units: Joules for energy, Kelvin for temperature, and Pascals for both fugacity and pressure.
Q4: Can this be used for liquids?
A: Yes, the same formula applies, but you must use appropriate fugacity values for the liquid phase.
Q5: What if I get a negative result?
A: Negative Gibbs energy indicates a spontaneous process under the given conditions.