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Definition: This calculator determines the number of metal-to-metal bonds present for every metal in an organometallic compound.
Purpose: It helps chemists understand the bonding structure in metal cluster compounds and organometallic complexes.
The calculator uses the formula:
Where:
Explanation: The formula is based on the 18-electron rule, subtracting the average valence electron count per metal from 18.
Details: Understanding metal-metal bonds is crucial for predicting compound stability, reactivity, and electronic structure in coordination chemistry.
Tips: Enter the total valence shell electron count (must be ≥ 0) and the number of metal atoms (must be > 0).
Q1: What is the 18-electron rule?
A: A rule used to predict the stability of organometallic compounds, where 18 valence electrons give a stable configuration.
Q2: How do I determine the VSE count?
A: Sum all valence electrons from the metal atoms and ligands in the complex.
Q3: Can this be used for any metal complex?
A: Primarily for transition metal clusters where metal-metal bonding is significant.
Q4: What does a fractional result mean?
A: It indicates the average number of bonds per metal atom in the cluster.
Q5: Are there exceptions to this rule?
A: Yes, some stable compounds don't follow the 18-electron rule, especially early transition metals.