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Rate Constant for First Order Reaction using Rate Constant for Zero Order Reaction Calculator

Formula Used:

\[ k_I = \frac{1}{\Delta t} \ln\left(\frac{C_{A0}}{C_{A0} - (k_0 \times \Delta t) - C_R}\right) \]

s
mol/m³
mol/(m³·s)
mol/m³

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1. What is Rate Constant for First Order Reaction using Rate Constant for Zero Order Reaction?

Definition: This calculator determines the rate constant for the first step in a two-step first order irreversible reaction series, using parameters from a zero order reaction.

Purpose: It helps chemical engineers and researchers analyze reaction kinetics in complex multi-step reactions.

2. How Does the Calculator Work?

The calculator uses the formula:

\[ k_I = \frac{1}{\Delta t} \ln\left(\frac{C_{A0}}{C_{A0} - (k_0 \times \Delta t) - C_R}\right) \]

Where:

Explanation: The formula calculates the first order rate constant by considering the consumption of reactant through both zero order reaction and intermediate formation.

3. Importance of Reaction Rate Constants

Details: Accurate determination of rate constants is crucial for reactor design, process optimization, and understanding reaction mechanisms.

4. Using the Calculator

Tips: Enter the time interval, initial concentration, zero order rate constant, and intermediate concentration. All values must be positive (except intermediate which can be zero).

5. Frequently Asked Questions (FAQ)

Q1: What is a first order reaction?
A: A reaction where the rate depends linearly on the concentration of one reactant.

Q2: What is a zero order reaction?
A: A reaction where the rate is independent of the reactant concentration.

Q3: When would I use this calculation?
A: When analyzing complex reactions with both zero and first order steps in series.

Q4: What units should I use?
A: Use seconds for time, mol/m³ for concentrations, and consistent units for rate constants.

Q5: What if I get an error?
A: Check that denominator (CA0-(k0*Δt)-CR) is positive and all inputs are valid.

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