Arrhenius Equation for Second Order Reaction:
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Definition: The Arrhenius equation describes how the rate constant (k) of a chemical reaction depends on temperature and activation energy.
Purpose: This calculator helps chemists and chemical engineers determine reaction rates for second-order reactions under different conditions.
The calculator uses the Arrhenius equation:
Where:
Explanation: The equation shows that reaction rates increase exponentially with temperature and decrease with higher activation energy.
Details: Accurate rate constants are essential for reactor design, process optimization, and understanding reaction mechanisms in chemical kinetics.
Tips: Enter the frequency factor (A), activation energy (Ea), and temperature (T). All values must be positive numbers.
Q1: What is a typical frequency factor value?
A: For second-order reactions, A typically ranges from 107 to 1011 m³/mol·s, but can vary widely.
Q2: How does temperature affect the rate constant?
A: Generally, a 10°C increase in temperature doubles or triples the reaction rate for many reactions.
Q3: What units should I use for activation energy?
A: Always use joules per mole (J/mol) for consistency with the gas constant.
Q4: Why is the gas constant important?
A: It provides the proper scaling between energy and temperature in the exponential term.
Q5: Can this calculator be used for other reaction orders?
A: No, this is specifically for second-order reactions. First-order reactions have different units for k.