Formula:
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Definition: Reduced Molar Volume for P-R Method of a fluid is computed from the ideal gas law at the substance's critical pressure and temperature per mole.
Purpose: It helps in understanding and predicting the behavior of real gases under various conditions using the Peng-Robinson equation of state.
The calculator uses the formula:
Where:
Explanation: The formula relates the actual molar volume to reduced properties using the Wohl parameter and critical properties of the substance.
Details: This calculation is essential in thermodynamics for predicting gas behavior, designing chemical processes, and modeling phase equilibria.
Tips: Enter the molar volume of real gas, Wohl parameter c, critical pressure, and critical temperature. All values must be positive numbers.
Q1: What is the Wohl parameter c?
A: Wohl parameter c is an empirical parameter characteristic to equation obtained from Wohl model of real gas.
Q2: How do I find critical properties of a substance?
A: Critical properties are typically found in chemical engineering reference books or thermodynamic databases for each substance.
Q3: What units should I use for inputs?
A: Use m³ for molar volume, Pascals for pressure, and Kelvin for temperature. The Wohl parameter is dimensionless.
Q4: Can this be used for all gases?
A: The calculation is most accurate for non-polar or slightly polar gases following Peng-Robinson behavior.
Q5: What does the reduced volume tell us?
A: It shows how the actual volume compares to the critical volume, helping predict gas behavior under different conditions.