Relative Supersaturation Formula:
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Definition: Relative Supersaturation is a measure that compares the actual concentration of a solute in a solution to the maximum concentration it can hold at a given temperature and pressure.
Purpose: It helps in understanding how much a solution is oversaturated, which is crucial in crystallization processes and material science.
The calculator uses the formula:
Where:
Explanation: The degree of supersaturation is divided by the equilibrium saturation value to determine how much the solution exceeds its stable concentration limit.
Details: This measurement is critical in controlling crystal growth rates, determining nucleation rates, and optimizing industrial crystallization processes.
Tips: Enter the degree of supersaturation and equilibrium saturation value (both in mol/m³). The equilibrium value must be greater than zero.
Q1: What does a relative supersaturation of 1 mean?
A: A value of 1 indicates the solution is exactly at its saturation point (ΔC = Cx). Values > 1 indicate supersaturation.
Q2: What are typical values in industrial processes?
A: Most industrial crystallization operates at φ values between 1.01 and 1.5, depending on the material and process requirements.
Q3: How does temperature affect these values?
A: Both ΔC and Cx are temperature-dependent. Higher temperatures generally increase Cx, while ΔC depends on the cooling or evaporation rate.
Q4: What units should be used?
A: Both inputs should be in consistent units (typically mol/m³). The result is dimensionless.
Q5: Can this be used for any solute-solvent system?
A: Yes, as long as you have accurate values for ΔC and Cx for your specific system at the working conditions.