Reverse Rate Constant Formula:
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Definition: This calculator determines the reverse rate constant (kr) using the dissociation rate constant (KD) and forward rate constant (kf).
Purpose: It helps chemists and chemical engineers calculate the rate of the reverse reaction in chemical kinetics.
The calculator uses the formula:
Where:
Explanation: The reverse rate constant is calculated as the product of the dissociation rate constant and the forward rate constant.
Details: Understanding reverse rate constants is crucial for modeling chemical equilibria and reaction kinetics in various chemical processes.
Tips: Enter the dissociation rate constant in mol/m³ and forward rate constant in s-1. All values must be > 0.
Q1: What is the relationship between KD, kf and kr?
A: The dissociation constant KD equals kr/kf, so kr = KD × kf.
Q2: What units should I use for the inputs?
A: Use mol/m³ for KD and s-1 for kf. The output will be in mol/(m³·s).
Q3: Can I use different concentration units?
A: Yes, but ensure all units are consistent. The calculator assumes SI units by default.
Q4: What's a typical value for KD?
A: KD values vary widely depending on the chemical system, from very small (strong binding) to very large (weak binding).
Q5: How does temperature affect these constants?
A: All rate constants are temperature-dependent, typically following the Arrhenius equation.