Home Back

Saturated Vapour Fugacity Coefficient of Comp. 2 using Sat. Pressure and Second Virial Coefficient Calculator

Formula Used:

\[ \phi_2^{sat} = \exp\left(\frac{B_{22} \times P_2^{sat}}{R \times T}\right) \]

Pa
K

Unit Converter ▲

Unit Converter ▼

From: To:

1. What is Saturated Vapour Fugacity Coefficient?

Definition: The Saturated Fugacity Coefficient of Component 2 is the ratio of the saturated fugacity of component 2 to the saturated pressure of component 2.

Purpose: This calculator determines the fugacity coefficient which accounts for non-ideal behavior of gases at saturation conditions.

2. How Does the Calculator Work?

The calculator uses the formula:

\[ \phi_2^{sat} = \exp\left(\frac{B_{22} \times P_2^{sat}}{R \times T}\right) \]

Where:

Explanation: The formula accounts for deviations from ideal gas behavior using the second virial coefficient.

3. Importance of Fugacity Coefficient Calculation

Details: Accurate fugacity coefficients are essential for phase equilibrium calculations in chemical engineering, particularly for vapor-liquid equilibrium systems.

4. Using the Calculator

Tips: Enter the second virial coefficient (B22) in m³, saturated pressure in Pascals, and temperature in Kelvin. All values must be positive.

5. Frequently Asked Questions (FAQ)

Q1: What is the physical meaning of the fugacity coefficient?
A: It measures how much a real gas deviates from ideal gas behavior, where φ=1 indicates ideal behavior.

Q2: Where can I find second virial coefficient values?
A: Second virial coefficients are typically found in chemical engineering handbooks or through experimental data.

Q3: What temperature range is this formula valid for?
A: This formula is generally valid for temperatures above the critical temperature of the component.

Q4: Why is the universal gas constant used here?
A: The universal gas constant provides consistent units when working in SI units (m³, Pa, K).

Q5: How does pressure affect the fugacity coefficient?
A: Generally, as pressure increases, the fugacity coefficient deviates more from 1 (more non-ideal behavior).

Saturated Vapour Fugacity Coefficient Calculator© - All Rights Reserved 2025