Temperature Coefficient Formula:
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Definition: The Temperature Coefficient (Φ) is the ratio of rate constants of a reaction at two temperatures differing by ten degrees Celsius.
Purpose: It helps quantify how temperature affects reaction rates in chemical kinetics.
The calculator uses the formula:
Where:
Explanation: The ratio shows how much the reaction rate increases when temperature increases by 10°C.
Details: Understanding Φ helps predict reaction behavior at different temperatures and is crucial for industrial process optimization.
Tips: Enter both rate constants in 1/s (same units). Values must be positive numbers.
Q1: What does a high Φ value indicate?
A: A high Φ means the reaction is very temperature-sensitive (rate increases significantly with temperature).
Q2: Typical range for Φ values?
A: Most reactions have Φ between 2-4, meaning rates double to quadruple per 10°C increase.
Q3: How is this related to Arrhenius equation?
A: Φ is an empirical approximation, while Arrhenius equation gives exact temperature dependence.
Q4: When would Φ be exactly 1?
A: When reaction rate is temperature-independent (extremely rare).
Q5: Can Φ be less than 1?
A: Yes, for reactions that slow down with increasing temperature (very unusual).