Van der Waals Constant Formula:
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The Van der Waals Constant a is a parameter in the Van der Waals equation that accounts for the intermolecular attractive forces between gas molecules. It helps correct the ideal gas law for real gas behavior.
The calculator uses the formula:
Where:
Explanation: This formula calculates the Van der Waals Constant a based on the inversion temperature and constant b of the gas.
Details: The Van der Waals Constant a is crucial for understanding real gas behavior, particularly in calculating corrections for intermolecular forces in gas equations of state.
Tips: Enter inversion temperature in Kelvin and Van der Waals Constant b in m³/mol. Both values must be positive numbers.
Q1: What is the physical significance of Van der Waals Constant a?
A: Constant a represents the magnitude of attractive forces between gas molecules. Larger values indicate stronger intermolecular attractions.
Q2: What is inversion temperature?
A: Inversion temperature is the temperature at which a gas neither heats nor cools when expanded through a throttle or porous plug.
Q3: How are Van der Waals constants determined experimentally?
A: They are typically determined by measuring P-V-T data for the gas and fitting it to the Van der Waals equation.
Q4: Do all gases have the same Van der Waals constants?
A: No, each gas has unique Van der Waals constants that depend on its molecular properties and intermolecular forces.
Q5: What are typical units for Van der Waals Constant a?
A: The SI units are Pa·m⁶/mol², but it can also be expressed in atm·L²/mol² or other pressure-volume² units.